Cu/Pd-catalyzed alkyne allylboration with racemic allylic carbonates proceeds with total inversion of configuration. Preliminary studies show that this synergistic catalysis can be used to perform a dynamic asymmetric allylic alkenylation that provides enantioenriched carboboration products.

中文翻译：

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过渡金属化是非对映和对映选择性协同铜/钯催化炔烃与外消旋烯丙基碳酸酯的烯丙基硼化的关键步骤

外消旋烯丙基碳酸酯的Cu / Pd催化炔烃烯丙基硼化与构型的完全转化进行。初步研究表明，这种协同催化作用可用于进行动态不对称烯丙基烯基化反应，从而提供对映体富集的碳硼化产物。