Gold-catalyzed domino reactions of alkynol and p-quinone methides: divergent synthesis of fused- and spiro-ketals,Organic Chemistry Frontiers

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Gold-catalyzed domino reactions of alkynol and p-quinone methides: divergent synthesis of fused- and spiro-ketals
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2020/02/19 , DOI: 10.1039/d0qo00022a
Wenxiu Mao _{1,

2,

3,

4} , Shiquan Lin _{1,

2,

3,

4} , Liang Zhang _{1,

2,

3,

4} , Haifeng Lu _{1,

2,

3,

4} , Jiong Jia _{1,

2,

3,

4} , Zhenghu Xu _{1,

2,

3,

4,

5}

Affiliation

An efficient gold-catalyzed domino reaction of alkynyl alcohols and p-quinone methides has been successfully developed. Divergent polycyclic fused- and spiro-ketals were synthesized in good yields under mild conditions from easily available starting materials in an atom-economical manner.

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