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An organic polymer CuPPc-derived copper oxide as a highly efficient electrocatalyst for water oxidation.
Chemical Communications ( IF 4.9 ) Pub Date : 2020/02/19 , DOI: 10.1039/d0cc00334d
Husileng Lee 1 , Xiujuan Wu , Xingqiang Wu , Xiaoxiao Wang , Qilun Ye , Licheng Sun
Affiliation  

Herein, we report a novel CuPPc (copper polymeric phthalocyanine)/CF (copper foam) nanoflake material, as precatalyst for the generation of an excellent water oxidation catalyst (WOC). Under optimized conditions, the CuPPc-derived Cu oxide affords a current density of 10 mA cm-2 under an overpotential (η) of 287 mV and sustains for at least 50 h in 1.0 M KOH. The strategy presented here is favorable to develop the electrocatalysts for water splitting.

中文翻译:

有机聚合物CuPPc衍生的氧化铜作为水氧化的高效电催化剂。

在本文中,我们报道了一种新型的CuPPc(铜聚合物酞菁)/ CF(铜泡沫)纳米片材料,作为产生优良水氧化催化剂(WOC)的预催化剂。在最佳条件下,源自CuPPc的Cu氧化物在287 mV的过电势(η)下提供10 mA cm-2的电流密度,并在1.0 M KOH中维持至少50 h。此处提出的策略有利于开发用于水分解的电催化剂。
更新日期:2020-03-31
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