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(C3H9NI)4AgBiI8: a direct-bandgap layered double perovskite based on a short-chain spacer cation for light absorption.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-02-19 , DOI: 10.1039/c9cc07796k
Yunpeng Yao 1 , Bo Kou , Yu Peng , Zhenyue Wu , Lina Li , Sasa Wang , Xinyuan Zhang , Xitao Liu , Junhua Luo
Affiliation  

A new iodide layered double perovskite (C3H9NI)4AgBiI8 (IPAB) has been developed based on a short-chain spacer cation, which is the first homologous compound in iodide double perovskites that adopt the Ruddlesden-Popper structure type. Importantly, IPAB is a promising environmentally friendly alternative to the recently rapidly progressing lead halide semiconductors owing to its narrow direct-bandgap of 1.87 eV and excellent stability.

中文翻译:

(C3H9NI)4AgBiI8:一种基于带隙间隔子阳离子的直接带隙层状双钙钛矿,用于光吸收。

基于短链间隔阳离子,开发了一种新的碘化物层状双钙钛矿(C3H9NI)4AgBiI8(IPAB),它是碘化物双钙钛矿中第一个采用Ruddlesden-Popper结构类型的同源化合物。重要的是,由于IPAB的1.87 eV窄的直接带隙和出色的稳定性,它是最近发展迅速的卤化铅半导体的有希望的环保选择。
更新日期:2020-03-12
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