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Preparation and Properties of Antimicrobial Poly(butylene adipate-co-terephthalate)/TiO2 Nanocomposites Films
Journal of Macromolecular Science Part B-Physics ( IF 1.4 ) Pub Date : 2020-01-14 , DOI: 10.1080/00222348.2020.1712045
Shuangling Luo 1 , Ping Zhang 2 , De Gao 2
Affiliation  

Poly(butylene adipate-co-terephthalate) (PBAT) nanocomposite films with various contents of nano-titanium dioxide (TiO2) and titanium dioxide doped silver (Ag-TiO2) were prepared by a solvent casting method. The TiO2 and Ag-TiO2 nanoparticles were surface-modified with silane coupling agents to improve their compatibility and dispersibility in the PBAT matrix. They were denoted as mTiO2 and mAg-TiO2, and were characrterized by Fourier transform infrared (FTIR) spectroscopy and transmission electron microscopy (TEM). The morphology of the PBAT nanocomposite films was studied by field emission scanning electron microscopy (FE-SEM). The crystallinity of the PBAT film increased upon the introduction of the nano-TiO2/Ag-TiO2. Its mechanical properties and gas barrier properties were also significantly improved. In addition, the PBAT/mTiO2 and PBAT/mAg-TiO2 nanocomposite films showed a strong antibacterial activity against Gram-negative (Escherichia coli) and Gram-positive (Staphylococcus aureus) food-borne pathogenic bacteria.



中文翻译:

抗菌聚己二酸丁二酯-对苯二甲酸对苯二甲酸酯/ TiO 2纳米复合薄膜的制备及性能

通过溶剂流延法制备了不同含量的纳米二氧化钛(TiO 2)和掺杂二氧化钛的银(Ag-TiO 2)的聚己二酸丁二醇酯-对苯二甲酸对苯二甲酸酯(PBAT)纳米复合膜。TiO 2和Ag-TiO 2纳米颗粒用硅烷偶联剂进行了表面改性,以提高它们在PBAT基质中的相容性和分散性。它们分别表示为mTiO 2和mAg-TiO 2,并通过傅里叶变换红外(FTIR)光谱和透射电子显微镜(TEM)进行了表征。通过场发射扫描电子显微镜(FE-SEM)研究了PBAT纳米复合膜的形貌。引入纳米TiO 2 / Ag-TiO 2后,PBAT膜的结晶度增加。其机械性能和气体阻隔性能也得到显着改善。此外,PBAT / mTiO 2和PBAT / MAG-TIO 2层纳米复合材料膜表现出对革兰氏阴性(很强的抗菌活性大肠杆菌)和革兰氏阳性(金黄色葡萄球菌)食源性致病菌。

更新日期:2020-02-18
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