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Catalytic transformation of CO2 into C1 chemicals using hydrosilanes as a reducing agent
Green Chemistry ( IF 9.8 ) Pub Date : 2020/02/17 , DOI: 10.1039/c9gc04342j
Yu Zhang 1, 2, 3, 4, 5 , Tong Zhang 1, 2, 3, 4, 5 , Shoubhik Das 1, 2, 3, 4, 5
Affiliation  

Utilization of CO2 for the synthesis of fine chemicals and pharmaceuticals has attracted tremendous attention. In fact, reductive transformation of CO2 is also an interesting approach in this direction. Obviously, using hydrogen as a reducing agent is the most promising pathway for this reductive transformation. However, alternative to hydrogen, hydrosilanes have been also in the forefront due to their ready availability, nontoxic nature and easy handling procedure. Based on all this information, this work summarizes the recent applications of hydrosilylation of CO2 using different catalysts such as metal catalysts, organocatalysts, and heterogeneous catalysts.

中文翻译:

使用氢硅烷作为还原剂将CO2催化转化为C1化学品

利用CO 2合成精细化学品和药物引起了极大的关注。实际上,在此方向上,CO 2的还原转化也是一种有趣的方法。显然,使用氢作为还原剂是该还原转化的最有希望的途径。但是,由于氢氢化合物易于使用,无毒且易于操作,因此氢替代氢也是最重要的。基于所有这些信息,这项工作总结了使用不同的催化剂(例如金属催化剂,有机催化剂和非均相催化剂)对CO 2进行氢化硅烷化的最新应用。
更新日期:2020-03-24
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