Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from simple, readily available feedstocks have become a cornerstone of modern synthetic organic chemistry. In light of the ever-increasing importance of aliphatic amines across the range of chemical sciences, this review aims to provide a concise overview of modern transition-metal catalyzed approaches to alkylamine synthesis and their functionalization. Selected examples of amine bond forming reactions include: (a) hydroamination and hydroaminoalkylation, (b) transition-metal catalyzed C(sp3)-H functionalization, and (c) transition-metal catalyzed visible-light-mediated light photoredox catalysis.

中文翻译：

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过渡金属催化合成脂肪胺的新策略。

能够从简单易得的原料中构建复杂脂族胺的过渡金属催化反应，已成为现代合成有机化学的基础。鉴于脂族胺在整个化学科学中的重要性日益提高，本综述旨在简要概述现代过渡金属催化的烷基胺合成及其功能化方法。胺键形成反应的选定实例包括：（a）加氢胺化和氢氨基烷基化，（b）过渡金属催化的C（sp3）-H官能化，和（c）过渡金属催化的可见光介导的光氧化还原催化。