Halogen bonds, which provide an intermolecular interaction with moderate strength and high directionality, have emerged as a promising tool in the repertoire of non‐covalent interactions. In this review, we provide a survey of the literature where halogen bonding was used for the fabrication of supramolecular networks on solid surfaces. The definitions of, and the distinction between halogen bonding and halogen‐halogen interactions are provided. Self‐assembled networks formed at the solution/solid interface and at the vacuum‐solid interface, stabilized in part by halogen bonding, are discussed. Besides the broad classification based on the interface at which the systems are studied, the systems are categorized further as those sustained by halogen‐halogen and halogen‐heteroatom contacts.

中文翻译：

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二维晶体工程中的卤素键合。

卤素键提供中等强度和高方向性的分子间相互作用，已成为非共价相互作用中很有前途的工具。在这篇综述中，我们对使用卤素键在固体表面上制造超分子网络的文献进行了调查。提供了卤素键合和卤素-卤素相互作用的定义和区别。讨论了在溶液/固体界面和真空-固体界面处形成的自组装网络，部分通过卤素键合稳定。除了基于研究系统的界面的广泛分类外，系统还进一步分类为通过卤素-卤素和卤素-杂原子接触维持的系统。