Solar energy, a clean and sustainable energy source, can be harvested and converted to solar fuel to meet the ever‐increasing energy demand. Integrating the photosensitizers and active catalytic sites into a single solid, metal–organic framework (MOF) with high void architectures and tunable chemical structures, is proposed as a promising platform for photocatalysis. However, compared with the traditional inorganic photocatalysts, the photocatalytic applications of MOFs are greatly hindered by its instability, especially the chemical instability. In this review, the background related to solar fuel production and MOFs are first discussed. Then, several strategies for designing stable MOFs are presented. Third, newly developed approaches for synthesizing highly efficient solar fuel production MOFs are summarized. Finally, the challenges and future perspectives using MOFs for solar fuel production are discussed. This review is expected to provide a deeper understanding of highly stable MOF design and new insights for the application of stable MOFs for solar fuel production.

中文翻译：

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探索用于光催化太阳能燃料的稳定的金属有机骨架的最新进展

可以收集清洁，可持续的能源即太阳能，并将其转换为太阳能，以满足不断增长的能源需求。提出将光敏剂和活性催化位点集成到具有高空隙结构和可调化学结构的单个固体，金属-有机框架（MOF）中，作为光催化的有希望的平台。然而，与传统的无机光催化剂相比，MOFs的不稳定性，特别是化学不稳定性，极大地阻碍了MOFs的光催化应用。在这篇综述中，首先讨论了与太阳能燃料生产和MOF相关的背景。然后，提出了几种设计稳定MOF的策略。第三，总结了合成高效太阳能燃料生产MOF的新方法。最后，讨论了使用MOF生产太阳能燃料的挑战和未来前景。预期该评论将为高度稳定的MOF设计提供更深入的了解，并为在太阳能燃料生产中应用稳定的MOF提供新的见解。