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Advanced Surface of Fibrous Activated Carbon Immobilized with FeO/TiO2 for Photocatalytic Evolution of Hydrogen under Visible Light
Chemical Engineering & Technology ( IF 2.1 ) Pub Date : 2020-03-10 , DOI: 10.1002/ceat.201900338
Ajit Sharma 1 , Doan Van Thuan 2 , Thanh-Dong Pham 3, 4 , Mai Hung Thanh Tung 5 , Nguyen Thi Thanh Truc 6 , Dai-Viet N. Vo 7
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FeO‐doped TiO2 nanoparticle photocatalysts were immobilized onto the surface of fibrous activated carbon (ACF) via a sol‐gel process. As an adsorbent and photocatalyst, FeO‐TiO2 on immobilized ACFs (FeO‐TiO2/ACF) greatly improved the photocatalysis rate of hydrogen production as compared with pure TiO2 and ACF‐TiO2 under UV irradiation and visible light. The addition of ACFs surface significantly reduced the photogenerated pairs of electrons‐hole recombination, thereby promoting the photocatalysis action of doped photo‐metal oxides of FeO‐TiO2. Co‐doping of FeO onto the lattice of the TiO2 approach can improve the absorption activity of visible light through photo‐metal oxide of TiO2 and further enhance hydrogen production under visible light. The photocatalytic fabrics (FeO‐TiO2/ACF) were effortlessly split out from the experimental solution for re‐utilization and exhibited high stability even after five complete regeneration cycles.

中文翻译:

FeO / TiO2固定的纤维状活性炭的高级表面在可见光下光催化氢的释放

FeO掺杂的TiO 2纳米颗粒光催化剂通过溶胶-凝胶过程固定在纤维状活性炭(ACF)的表面上。作为吸附剂和光催化剂,FeO的-TIO 2上固定的ACF(FeO的-TIO 2 / ACF)与纯的TiO相比大大提高了氢气生产的光催化作用速率2和ACF-TIO 2 UV照射和可见光下。ACFs表面的添加显着减少了光生电子-空穴复合对,从而促进了FeO-TiO 2掺杂光金属氧化物的光催化作用。FeO在TiO 2晶格上的共掺杂该方法可以通过TiO 2的光金属氧化物提高可见光的吸收活性,并进一步提高可见光下的产氢量。将光催化织物(FeO-TiO 2 / ACF)轻松地从实验溶液中分离出来,以进行再利用,即使经过5个完整的再生循环,它仍具有很高的稳定性。
更新日期:2020-03-10
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