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The gibbs-thomson effect in dilute binary systems
Metallurgical and Materials Transactions A ( IF 1.985 ) Pub Date : 2002 , DOI: 10.1007/s11661-002-0230-2
Ma Qian

A constructed molar Gibbs energy diagram was used to introduce a general description of the Gibbs-Thomson effect in dilute binary system. The analysis was based on the assumption that the common tangent approach is applicable to the solid-solid systems analyzed. The solubility of a precipitate, which was commonly referred to as the composition of the matrix in equilibrium with the precipitate in the presence of a curved interface, was studied. The equilibrium between the matrix and the precipitate was illustrated by constructing a molar Gibbs free energy diagram. The analysis was found to approximate the solid-solid systems, as if the matrix were liquid.
更新日期:2020-01-01

 

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