AbstractA new molybdenum containing oxyfluoride, BaMoOF5, space group Cmcm with lattice parameters of a = 7.1445(3), b = 6.7894(3), c = 10.1969(4), was synthesized via a mild hydrothermal crystal growth method. The synthesis resulted in high-quality single crystals of the title material, which were characterized by single-crystal X-ray diffraction. The structure is discussed in detail.Graphical AbstractA new Mo(V) oxyfluoride, BaMoOF5, was synthesized via a mild hydrothermal route that included an in-situ reduction step to reduce molybdenum from a starting oxidation state of 6+ to 5+.

中文翻译：

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在 BaMoOF5 的合成中利用原位还原

摘要 通过温和的水热晶体生长方法合成了一种新的含氟氧钼，BaMoOF5，空间群Cmcm，晶格参数a = 7.1445(3), b = 6.7894(3), c = 10.1969(4)。合成产生了标题材料的高质量单晶，其特征在于单晶 X 射线衍射。详细讨论了结构。图形摘要通过温和的水热路线合成了一种新的 Mo(V) 氟氧化物 BaMoOF5，该路线包括原位还原步骤，将钼从 6+ 的起始氧化态还原为 5+。