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An ordered network polymer of bicontinuous cubic structure resulting from photo-polymerization of a coil-rod-coil molecule self-assembly
Macromolecular Research ( IF 2.4 ) Pub Date : 2009 , DOI: 10.1007/bf03218693
Keli Zhong , Tie Chen , Bingzhu Yin , Long Yi Jin

An unusual strategy to generate an ordered network polymer from the self-assembly of reactive coil-rod-coil molecules was successfully achieved. The bicontinuous cubic structure of molecule4 was maintained by cross-linking the photo-polymerization self-assembly of4 in the liquid crystalline state. The result suggests that an approach to control a reactive supramolecular molecule structure and conversion to a polymer allows a novel, highly ordered 3-D nanostructural polymer to be produced.

中文翻译:

线圈-棒-线圈分子自组装的光聚合产生的双连续立方结构的有序网络聚合物

成功地实现了一种从反应性线圈-棒-螺旋分子的自组装产生有序网络聚合物的不寻常策略。通过使处于液晶状态的4的光聚合自组装体交联来维持分子4的双连续立方结构。结果表明,控制反应性超分子分子结构并将其转化为聚合物的方法可以生产出新颖的,高度有序的3-D纳米结构聚合物。
更新日期:2020-09-14
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