当前位置: X-MOL 学术Chinese. J. Polym. Sci. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales
Chinese Journal of Polymer Science ( IF 4.3 ) Pub Date : 2019-09-12 , DOI: 10.1007/s10118-019-2313-1
Wei Zhao , Tian-Pin Wang , Jia-Li Wu , Ru-Ping Pan , Xiang-Yang Liu , Xi-Kui Liu

Here, through the synergism between kinetic dynamic imine-exchange control and thermodynamic control, rarely observed compressible, porous, crystalline covalent organic framework (COF) aerogels were synthesized, the mechanism behind which is a framework crystallization induced self-assembly (FCISA) process. The prepared COF aerogel possessed extremely high BET surface over 2000 m2·g−1 and high maximum equilibrium adsorption capacity toward bisphenol-A of 699 mg·g−1 in aqueous solution.



中文翻译:

通过骨架结晶诱导的自组装的整体共价有机骨架气凝胶:朝着所有长度尺度的骨架材料合成前进

在这里,通过动力学动态亚胺交换控制和热力学控制之间的协同作用,合成了很少观察到的可压缩,多孔,结晶的共价有机骨架(COF)气凝胶,其背后的机制是骨架结晶诱导的自组装(FCISA)过程。制备的COF气凝胶在2000m 2 ·g -1内具有极高的BET表面,并且在水溶液中对双酚A的最大平衡吸附容量为699 mg·g -1

更新日期:2019-09-12
down
wechat
bug