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Synthesis and Characterization Ag Nanoparticles Supported on Bi 2 WO 6 Nanoplates for Enhanced Visible-Light-Driven Photocatalytic Degradation of Rhodamine B
Journal of Inorganic and Organometallic Polymers and Materials ( IF 4 ) Pub Date : 2019-07-06 , DOI: 10.1007/s10904-019-01254-5
Anukorn Phuruangrat , Paveen-On Keereesaensuk , K. Karthik , Phattranit Dumrongrojthanath , Nuengruethai Ekthammathat , Somchai Thongtem , Titipun Thongtem

Heterostructure Ag/Bi2WO6 nanocomposites with different weight contents of Ag nanoparticles for photodegradation of rhodamine B (RhB) were successfully synthesized by solution precipitate-deposition method using sodium borohydride (NaBH4) as a reducing agent. The results of X-ray diffraction (XRD) and transmission electron microscopy (TEM) certify the successful synthesis of cubic Ag nanoparticles supported on the surface of orthorhombic Bi2WO6 nanoplates. X-ray photoelectron spectroscopy (XPS) revealed the presence of metallic Ag species supported on Bi2WO6 nanoplates. The photocatalytic performance of heterostructure Ag/Bi2WO6 nanocomposites were investigated through the degradation of RhB under visible light irradiation. In this research, Ag/Bi2WO6 nanocomposites exhibited excellent chemical stability and recyclability under visible light irradiation. The 5 wt% Ag/Bi2WO6 showed the highest photodegradation of RhB due to the Ag nanoparticles acting as an electron trapper, to restrain the recombination of photo-induced electrons and holes, to improve the charge separation, and to enhance the photocatalytic performance of Bi2WO6.

中文翻译:

Bi 2 WO 6纳米板上负载的Ag纳米粒子的合成及表征,用于增强罗丹明B的可见光驱动光催化降解。

以硼氢化钠(NaBH 4)为还原剂,通过溶液沉淀法成功地合成了不同重量比的纳米级Ag纳米颗粒的复合结构Ag / Bi 2 WO 6纳米复合物,用于光化学降解罗丹明B(RhB)。X射线衍射(XRD)和透射电子显微镜(TEM)的结果证明了正交晶Bi 2 WO 6纳米板表面负载的立方Ag纳米颗粒的成功合成。X射线光电子能谱(XPS)揭示了Bi 2 WO 6纳米板上负载的金属Ag的存在。Ag / Bi 2 WO异质结构的光催化性能通过在可见光照射下降解RhB来研究6种纳米复合材料。在这项研究中,Ag / Bi 2 WO 6纳米复合材料在可见光照射下表现出优异的化学稳定性和可回收性。5wt%的Ag / Bi 2 WO 6表现出最高的RhB光降解,这是由于Ag纳米粒子充当电子陷阱,抑制了光诱导电子和空穴的复合,改善了电荷分离,并增强了光催化作用。 Bi 2 WO 6的性能。
更新日期:2019-07-06
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