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Photocatalytic Selective Oxidation of Organic Compounds in Graphitic Carbon Nitride Systems: A Review
Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2019-07-01 , DOI: 10.1007/s11237-019-09607-4
A. L. Stroyuk , A. E. Raevskaya , S. Ya. Kuchmy

Recent work is reviewed concerning photocatalytic systems derived from graphitic carbon nitride (GCN) for the selective oxidation of various organic compounds including saturated and unsaturated hydrocarbons, alcohols, and organic sulfides. Examples are given for oxidative coupling of a series of organic compounds with the formation of carbon–nitrogen and carbon–carbon bonds as well as cyclization. The properties of various GCN samples were examined, including bulk, mesoporous, layered, and individual materials as well as samples modified with organic compounds, samples doped with metals and nonmetals, and GCN-derived composite materials. The outlook for future research in this field is given at the conclusion.

中文翻译:

石墨氮化碳体系中有机化合物的光催化选择性氧化:综述

综述了最近关于源自石墨氮化碳 (GCN) 的光催化系统用于选择性氧化各种有机化合物,包括饱和和不饱和烃、醇和有机硫化物的工作。给出了一系列有机化合物的氧化偶联与碳-氮和碳-碳键的形成以及环化的例子。检查了各种 GCN 样品的性质,包括块状、介孔、层状和单个材料以及用有机化合物改性的样品、掺杂金属和非金属的样品以及 GCN 衍生的复合材料。结论部分给出了该领域未来研究的展望。
更新日期:2019-07-01
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