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Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of Ru-Containing Catalysts Based on New Zeolite-Like Materials
Catalysis in Industry Pub Date : 2019-06-25 , DOI: 10.1134/s2070050419020065 Yu. V. Kurchenko , I. L. Simakova , Yu. S. Demidova , V. N. Panchenko , M. N. Timofeeva
中文翻译:
新型沸石类材料的含钌催化剂在糠醛加氢制糠醇中的应用
更新日期:2019-06-25
Catalysis in Industry Pub Date : 2019-06-25 , DOI: 10.1134/s2070050419020065 Yu. V. Kurchenko , I. L. Simakova , Yu. S. Demidova , V. N. Panchenko , M. N. Timofeeva
Abstract
Catalytic liquid-phase hydrogenation of furfural to commercially important furfuryl alcohol was studied in the presence of Ru-containing catalysts based on Sibunit and zeo-type materials, such as nickel phosphate molecular sieves (VSB-5 and Fe-VSB-5) and zirconium-containing metal–organic frameworks (UiO-66(Zr)-R, R = H and NH2), at 30 and 50°C and 5–25 atm of hydrogen. The yield of furfuryl alcohol was found to depend on the nature of the support and increases in the following order: Ru/UiO-66(Zr)-NH2 < Ru/UiO-66(Zr) < Ru/Fe-VSB-5 < Ru/VSB-5. The effect of hydrogen pressure and temperature on the selectivity toward furfuryl alcohol was investigated.中文翻译:
新型沸石类材料的含钌催化剂在糠醛加氢制糠醇中的应用