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Synthesis of gem-dichlorocyclopropane and 1,3-dioxane derivatives from divinylbenzene
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2019-11-01 , DOI: 10.1007/s11172-019-2671-4
G. Z. Raskil’dina , Yu. G. Borisova , L. V. Spirikhin , S. S. Zlotskii

The Prins reaction and cyclopropanation of the light fraction obtained by distillation of the technical grade divinylbenzene and consisting of a mixture of 1,3- and 1,4-divinylbenzenes with admixture of 3- and 4-ethylstyrenes were studied. These reactions quantitatively give the corresponding gem-dichlorocyclopropane and 1,3-dioxane benzene derivatives. The structures of the synthesized compounds were confirmed by NMR spectroscopy and mass spectrometry.

中文翻译:

从二乙烯基苯合成偕二氯环丙烷和 1,3-二恶烷衍生物

研究了通过蒸馏工业级二乙烯基苯并由 1,3- 和 1,4- 二乙烯基苯与 3- 和 4- 乙基苯乙烯的混合物组成的轻馏分的 Prins 反应和环丙烷化。这些反应定量地得到相应的偕二氯环丙烷和 1,3-二恶烷苯衍生物。合成化合物的结构经核磁共振谱和质谱证实。
更新日期:2019-11-01
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