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The problem of optical isomerism and the interpretation of quantum mechanics
Foundations of Chemistry ( IF 0.9 ) Pub Date : 2019-01-01 , DOI: 10.1007/s10698-018-09330-3
Juan Camilo Martínez González

When young Kant meditated upon the distinction between his right and left hands, he could not foresee that the problem of incongruent counterparts would revive in the twentieth century under a new form. In the early days of quantum chemistry, Friedrich Hund developed the so-called Hund paradox that arises from the supposed inability of quantum mechanics to account for the difference between enantiomers. In this paper, the paradox is expressed as a case of quantum measurement, stressing that decoherence does not offer a way out of the problem. The main purpose is to argue for the need to adopt a clear interpretation of quantum mechanics in order to solve the paradox. In particular, I claim that the Modal-Hamiltonian Interpretation, which conceives measurement as a breaking-symmetry process, supplies the tools required to explain the dextro-rotation or levo-rotation properties of optical isomers.

中文翻译:

光学异构问题与量子力学的解释

年轻的康德在思考左右手的区别时,没有预见到手不协调的问题会以一种新的形式在 20 世纪卷土重来。在量子化学的早期,弗里德里希·洪德 (Friedrich Hund) 提出了所谓的洪德悖论,该悖论源于假设量子力学无法解释对映异构体之间的差异。在本文中,悖论被表述为量子测量的一个案例,强调退相干并没有提供解决问题的方法。主要目的是论证需要采用对量子力学的清晰解释以解决悖论。特别是,我声称,将测量视为打破对称过程的模态-汉密尔顿解释,
更新日期:2019-01-01
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