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Metallacycle Transfer and its Link to Light‐Emitting Materials and Conjugated Polymers
The Chemical Record ( IF 6.6 ) Pub Date : 2019-12-13 , DOI: 10.1002/tcr.201900095
Eric Rivard 1
Affiliation  

Major advances in optoelectronic technologies (e. g., solar cells, organic light‐emitting diodes, etc…) are prefaced by the discovery of new synthetic methodologies. In this review, the key role of the Fagan‐Nugent reaction in enabling our team (and others) to gain access to new building blocks for luminescent materials and conjugated polymers bearing p‐block elements will be described. The Fagan‐Nugent reaction is extremely powerful as a synthetic tool since the efficient zirconium‐element atom exchange involved affords a wide range of unsaturated inorganic heterocycles of controllable composition and function.

中文翻译:

金属环转移及其与发光材料和共轭聚合物的联系

光电子技术(例如,太阳能电池,有机发光二极管等)的重大进步以发现新的合成方法为序。在这篇综述中,将描述Fagan-Nugent反应在使我们的团队(和其他人)获得发光材料和带有p嵌段元素的共轭聚合物的新结构块方面的关键作用。Fagan-Nugent反应作为一种合成工具极为强大,因为所涉及的有效锆元素原子交换提供了可控制组成和功能的各种不饱和无机杂环。
更新日期:2019-12-13
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