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Soft-Matter Nanotubes: A Platform for Diverse Functions and Applications.
Chemical Reviews ( IF 62.1 ) Pub Date : 2020-02-04 , DOI: 10.1021/acs.chemrev.9b00509
Toshimi Shimizu 1 , Wuxiao Ding 1 , Naohiro Kameta 1
Affiliation  

Self-assembled organic nanotubes made of single or multiple molecular components can be classified into soft-matter nanotubes (SMNTs) by contrast with hard-matter nanotubes, such as carbon and other inorganic nanotubes. To date, diverse self-assembly processes and elaborate template procedures using rationally designed organic molecules have produced suitable tubular architectures with definite dimensions, structural complexity, and hierarchy for expected functions and applications. Herein, we comprehensively discuss every functions and possible applications of a wide range of SMNTs as bulk materials or single components. This Review highlights valuable contributions mainly in the past decade. Fifteen different families of SMNTs are discussed from the viewpoints of chemical, physical, biological, and medical applications, as well as action fields (e.g., interior, wall, exterior, whole structure, and ensemble of nanotubes). Chemical applications of the SMNTs are associated with encapsulating materials and sensors. SMNTs also behave, while sometimes undergoing morphological transformation, as a catalyst, template, liquid crystal, hydro-/organogel, superhydrophobic surface, and micron size engine. Physical functions pertain to ferro-/piezoelectricity and energy migration/storage, leading to the applications to electrodes or supercapacitors, and mechanical reinforcement. Biological functions involve artificial chaperone, transmembrane transport, nanochannels, and channel reactors. Finally, medical functions range over drug delivery, nonviral gene transfer vector, and virus trap.

中文翻译:

软物质纳米管:多种功能和应用的平台。

与诸如碳和其他无机纳米管之类的硬质纳米管相比,由单个或多个分子成分制成的自组装有机纳米管可分为软质纳米管(SMNT)。迄今为止,使用合理设计的有机分子的各种自组装过程和精心设计的模板程序已经产生了合适的管状结构,具有确定的尺寸,结构复杂性和预期功能和应用的层次结构。在本文中,我们全面讨论了作为散装材料或单个组件的各种SMNT的每种功能和可能的应用。这篇综述重点介绍了过去十年中的宝贵贡献。从化学,物理,生物学和医学应用的角度讨论了15种不同的SMNT家族,以及作用域(例如,内部,墙壁,外部,整个结构和纳米管的集合)。SMNT的化学应用与封装材料和传感器有关。SMNTs有时会进行形态转换,同时还充当催化剂,模板,液晶,水/有机凝胶,超疏水表面和微米级引擎的行为。物理功能涉及铁电/压电和能量迁移/存储,从而导致其应用于电极或超级电容器以及机械加固。生物功能涉及人工伴侣,跨膜转运,纳米通道和通道反应器。最后,医疗功能涵盖药物输送,非病毒基因转移载体和病毒陷阱。SMNT的化学应用与封装材料和传感器有关。SMNTs有时会进行形态转换,同时还充当催化剂,模板,液晶,水/有机凝胶,超疏水表面和微米级引擎的行为。物理功能涉及铁电/压电和能量迁移/存储,从而导致其应用于电极或超级电容器以及机械加固。生物功能涉及人工伴侣,跨膜转运,纳米通道和通道反应器。最后,医疗功能涵盖药物输送,非病毒基因转移载体和病毒陷阱。SMNT的化学应用与封装材料和传感器有关。SMNTs有时会进行形态转换,同时还充当催化剂,模板,液晶,水/有机凝胶,超疏水表面和微米级引擎的行为。物理功能涉及铁电/压电和能量迁移/存储,从而导致其应用于电极或超级电容器以及机械加固。生物功能涉及人工伴侣,跨膜转运,纳米通道和通道反应器。最后,医疗功能涵盖药物输送,非病毒基因转移载体和病毒陷阱。水/有机凝胶,超疏水表面和微米级引擎。物理功能涉及铁电/压电和能量迁移/存储,从而导致其应用于电极或超级电容器以及机械加固。生物功能涉及人工伴侣,跨膜转运,纳米通道和通道反应器。最后,医疗功能涵盖药物输送,非病毒基因转移载体和病毒陷阱。水/有机凝胶,超疏水表面和微米级引擎。物理功能涉及铁电/压电和能量迁移/存储,从而导致其应用于电极或超级电容器以及机械加固。生物功能涉及人工伴侣,跨膜转运,纳米通道和通道反应器。最后,医疗功能涵盖药物输送,非病毒基因转移载体和病毒陷阱。
更新日期:2020-02-04
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