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Non-contact fluorescence intensity ratio optical thermometer based on Yb3+/Nd3+ codoped Bi4Ti3O12 microcrystals
Journal of Luminescence ( IF 3.6 ) Pub Date : 2020-05-01 , DOI: 10.1016/j.jlumin.2020.117095
Hao Chen , Gongxun Bai , Qinghua Yang , Youjie Hua , Shiqing Xu , Liang Chen

Abstract Optical thermometer based on the non-contact fluorescence intensity ratio technique of two thermally-couple levels has huge potential applications in many fields, such as the electric power industry and in-situ physiological measurements. In the paper, the Yb3+/Nd3+ codoped Bi4Ti3O12 nanocrystal ratio thermometer has prepared by solid-phase sintering. The two thermally-couple levels are Nd3+:4F7/2 (emission peak around 753 nm) and Nd3+:4F5/2 (emission peak at 805 nm), respectively. The optical thermometer has based on the upconversion in near-infrared luminescence under 980 nm excitation with low power of 1.87 W/cm2. Due to the relatively low pump power, the effect of the excitation heat effect on the material is reduced. This resulted in a relatively high relative sensitivity (SR = 1% K−1) in the temperature range of 323–573 K. In addition to the characteristics, the excellent repeatability (σ = 1.5%) of the fluorescence intensity ratio between the two Nd3+ emission peaks makes Yb3+/Nd3+ codoped Bi4Ti3O12 microcrystals a promising non-contact near-infrared ratio thermometer.

中文翻译:

基于Yb3+/Nd3+共掺杂Bi4Ti3O12微晶的非接触式荧光强度比光学温度计

摘要 基于非接触式两级热电偶荧光强度比技术的光学温度计在电力工业、原位生理测量等诸多领域具有巨大的应用潜力。本文采用固相烧结法制备了Yb3+/Nd3+共掺杂Bi4Ti3O12纳米晶比温度计。两个热偶能级分别是 Nd3+:4F7/2(发射峰值在 753 nm 附近)和 Nd3+:4F5/2(发射峰值在 805 nm)。光学温度计基于近红外发光在 980 nm 激发下的上转换,低功率为 1.87 W/cm2。由于相对较低的泵浦功率,减少了激发热效应对材料的影响。这导致在 323-573 K 的温度范围内具有相对较高的相对灵敏度 (SR = 1% K−1)。
更新日期:2020-05-01
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