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Preparation of a 3D multi-branched chelate adsorbent for high selective adsorption of uranium(VI): Acrylic and diaminomaleonitrile functionalized waste hemp fiber
Reactive & Functional Polymers ( IF 5.1 ) Pub Date : 2020-02-03 , DOI: 10.1016/j.reactfunctpolym.2020.104512
Ziheng Bai , Qi Liu , Dalei Song , Hongsen Zhang , Jingyuan Liu , Rongrong Chen , Jing Yu , Rumin Li , Jun Wang

Uranium(VI) is an important strategic resource in the development of nuclear energy with 4.5 billion tons in the seawater. However, because of the low concentration of U(VI) and the presence of multiple competing ions in seawater. It is a significant challenge for extracting U(VI) from seawater. In this study, a series of multi-branched HF-PAA-AOn(n =1,2,3,4,5) adsorption materials were prepared for the extraction of U(VI) from solution, and the adsorption properties of the adsorbents were investigated by batch experiments. The experimental results indicated that the HF-PAA-AO5 material exhibits an excellent removal rate and the maximum adsorption capacity of HF-PAA-AO5 is of 550.28 mg/g. Moreover, the adsorbent still maintains a high adsorption efficiency after five adsorption-desorption recycles. Meanwhile, the adsorbent showed superior selectivity and adsorption properties (removal rate > 89%) in modified artificial seawater. Therefore, the HF-PAA-AO5 composite is considered to be a favorable potential adsorbent for capturing U(VI) from seawater.



中文翻译:

用于高选择性吸附铀(VI)的3D多支螯合吸附剂的制备:丙烯酸和二氨基马来腈官能化的废麻纤维

铀(VI)是发展核能的重要战略资源,海水中的铀含量为45亿吨。但是,由于U(VI)的浓度低,并且海水中存在多个竞争离子。从海水中提取U(VI)是一项重大挑战。在这项研究中,制备了一系列多支HF-PAA-AO n(n  = 1,2,3,4,5)吸附材料,用于从溶液中萃取U(VI),以及该吸附剂的吸附性能。通过分批实验研究吸附剂。实验结果表明,HF-PAA-AO 5材料表现出优异的去除速率和HF-PAA-AO的最大吸附容量5是550.28 mg / g。而且,在五个吸附-解吸循环之后,吸附剂仍保持高吸附效率。同时,该吸附剂在改性人工海水中表现出优异的选择性和吸附性能(去除率> 89%)。因此,HF-PAA-AO 5复合材料被认为是从海水中捕获U(VI)的有利潜在吸附剂。

更新日期:2020-02-03
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