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Discriminative detection of mercury (II) and hydrazine using a dual-function fluorescent probe.
Luminescence ( IF 2.9 ) Pub Date : 2020-01-30 , DOI: 10.1002/bio.3781
Xiaoming Wu 1 , Yanan Li 1 , Shaoxiang Yang 1 , Hongyu Tian 1 , Baoguo Sun 1
Affiliation  

A dual‐function fluorescent probe (Probe 1 ) was developed for discriminative detection of Hg2+ and N2H4. Probe 1 could discriminatively detect Hg2+ and N2H4 through two different reaction sites, with the mechanism for Probe 1 for Hg2+ depending on a desulfurization reaction and for N2H4 depending on the Schiff‐base reaction. N2H4 had minimal effect on Hg2+ detection in dimethyl sulfoxide (DMSO)/H2O solution, but Hg2+ could interfere with N2H4 detection in DMSO/buffer solution. Different concentrations of Hg2+ and N2H4 resulted in different blue shades of Probe 1 test strips, and the shade of blue was different with the same concentration of Hg2+ or N2H4, as observed under ultraviolet light at 365 nm wavelength.

中文翻译:

使用双功能荧光探针判别检测汞(II)和肼。

开发了一种用于区分检测Hg 2+和N 2 H 4的双功能荧光探针(探针1)。探针1可以通过两个不同的反应位点判别检测Hg 2+和N 2 H 4,探针1的Hg 2+机理取决于脱硫反应,而N 2 H 4的机理取决于Schiff碱反应。N 2 H 4对二甲基亚砜(DMSO)/ H 2 O溶液中Hg 2+的检测影响最小,但是Hg2+可能会干扰DMSO /缓冲溶液中N 2 H 4的检测。Hg 2+和N 2 H 4的浓度不同,导致探针1测试条的蓝色阴影不同,而Hg 2+或N 2 H 4的浓度相同时,蓝色阴影在365紫外线下观察到纳米波长。
更新日期:2020-01-30
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