The synthesis and study of the structure and properties (by methods of X-ray structural analysis, DTA, IR, Raman, and ¹H, ¹⁹F NMR, including ¹⁹F MAS NMR) of a new crystal hydrate of the composition ZnZr₂F₁₀∙6H₂O (1) have been performed.

The compound 1 crystallizes in the monoclinic system with the following unit cell parameters: a = 6.5628(2), b = 10.2031(4), c = 9.0965(4) Å, β = 100.532(1)°, sp.gr. C2/m, Z = 2. The crystal structure is built of flat cross-linked anion layers of the composition ${{}_{\infty }{}^2\left[\text{Z}{\text{r}}_2{\text{F}}_{10}\right]}^{2-}$and octahedral [Zn(H₂O)₆]²⁺ cations. The complex cations and anions are linked in the structure into a three-dimensional network by O–H···F and O–H···O hydrogen bonds.

It has been established that decomposition of 1 in temperature range 50-850 °C in air proceeds stepwise through the following stages: ZnZr₂F₁₀∙6H₂O → ZnZr₂F₁₀∙4H₂O → ZnZr₂F₁₀∙2H₂O → ZnZr₂OF₈ with formation of the mixture of the final products ZnO and ZrO₂. The vibrational and NMR spectroscopy data for the initial compound and intermediate products of its decomposition have been obtained, systematized, and summarized.

组成为ZnZr ₂ F的新型晶体水合物的合成和结构和性能研究（通过X射线结构分析，DTA，IR，拉曼和¹ H，¹⁹ F NMR，包括¹⁹ F MAS NMR）已执行₁₀ ∙6H ₂ O（1）。

化合物1在单斜晶系统中具有以下晶胞参数结晶：a  = 6.5628（2），b  = 10.2031（4），c  = 9.0965（4）Å，β  = 100.532（1）°，sp.gr. C2 / m，Z  =2。晶体结构由组成平坦的交联阴离子层组成${{}_{\infty }{}^2\left[\text{ž}{\text{[R}}_2{\text{F}}_{10}\right]}^{2-}$和八面体[Zn（H ₂ O）₆ ] ²⁺阳离子。复杂的阳离子和阴离子在结构中通过OH···F和OH···O氢键连接成三维网络。

已经确定，在空气中温度范围为50-850°C的1中，分解过程逐步进行：ZnZr ₂ F ₁₀ ∙6H ₂ O→ZnZr ₂ F ₁₀ ∙4H ₂ O→ZnZr ₂ F ₁₀ ∙2H ₂ O→ZnZr ₂ OF ₈形成最终产物ZnO和ZrO ₂的混合物。已获取，系统化和总结了其分解的初始化合物和中间产物的振动和NMR光谱数据。