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Potassium promoted Y2O3-Co3O4 catalysts for N2O decomposition
Catalysis Communications ( IF 3.7 ) Pub Date : 2020-01-28 , DOI: 10.1016/j.catcom.2020.105948
Tianqi Zhao , Yulin Li , Qiang Gao , Zhiying Liu , Xiufeng Xu

A Y2O3-Co3O4 catalyst was prepared by an innovative co-precipitation method at the solution boiling temperature, and tested for the N2O decomposition reaction. The catalyst exhibited a higher catalytic activity than that prepared by the common co-precipitation method at 90 °C. In addition, the catalytic performance of the Y2O3-Co3O4 catalyst was further enhanced by K-promoter, which might be related to the weakening of CoO bond and higher concentration of adsorbed oxygen (Oα) on the catalyst surface. Even under the co-presence of oxygen and steam in the feed stream, the K/Y2O3-Co3O4 catalyst showed good catalytic stability and maintained 100% conversion of N2O after a continuous reaction at 400 °C for 30 h.



中文翻译:

钾促进的N 2 O分解用Y 2 O 3 -Co 3 O 4催化剂

通过创新的共沉淀法在溶液沸腾温度下制备了AY 2 O 3 -Co 3 O 4催化剂,并进行了N 2 O分解反应的测试。该催化剂比在90°C下通过常规共沉淀法制备的催化剂具有更高的催化活性。此外,钾促进剂进一步提高了Y 2 O 3 -Co 3 O 4催化剂的催化性能,这可能与Co O键的弱化和高浓度的吸附氧()在催化剂表面上。即使在进料流中同时存在氧气和蒸汽,K / Y 2 O 3 -Co 3 O 4催化剂也表现出良好的催化稳定性,并且在400°C下连续反应400°C后仍保持100%的N 2 O转化率。30小时

更新日期:2020-01-30
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