当前位置: X-MOL 学术Transit. Met. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Synthesis, crystal structure and properties of copper(II) complexes with triethanolamine and carboxylic acids (succinic, salicylic, cinnamic)
Transition Metal Chemistry ( IF 1.7 ) Pub Date : 2019-10-24 , DOI: 10.1007/s11243-019-00359-7
Y. Kondratenko , A. A. Zolotarev , I. Ignatyev , V. Ugolkov , T. Kochina

The interaction of triethanolamine (TEA) with Cu(II) salts of salicylic, cinnamic and succinic acids was studied for the first time. The structure of the synthesized complexes was investigated by single-crystal X-ray diffraction. TEA complexes with Cu(II) salicylate ( 1 ) and cinnamate ( 2 ) are binuclear mixed ligand complexes, but interaction of TEA with Cu(II) succinate leads to the formation of cationic mononuclear complex—[Cu(TEA) 2 ](C 4 H 4 O 4 ) ( 3 ). Cu(II) complexes 1 – 3 were also characterized by physicochemical and spectroscopic methods. Their antimicrobial activity was investigated.

中文翻译:

铜(II)与三乙醇胺和羧酸(琥珀酸、水杨酸、肉桂酸)络合物的合成、晶体结构和性质

首次研究了三乙醇胺 (TEA) 与水杨酸、肉桂酸和琥珀酸的 Cu(II) 盐的相互作用。通过单晶X射线衍射研究了合成配合物的结构。TEA 与水杨酸铜 (1) 和肉桂酸 (2) 的配合物是双核混合配体配合物,但 TEA 与琥珀酸铜 (II) 的相互作用导致形成阳离子单核配合物——[Cu(TEA) 2 ](C 4 H 4 O 4 ) ( 3 )。Cu(II) 配合物 1-3 还通过物理化学和光谱方法进行了表征。研究了它们的抗微生物活性。
更新日期:2019-10-24
down
wechat
bug