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Boosting of Soot Combustion on Alkaline Mn/ZrO 2 Nanostructures
Topics in Catalysis ( IF 3.6 ) Pub Date : 2020-01-25 , DOI: 10.1007/s11244-020-01224-z
R. Camposeco , S. Castillo , N. Nava , R. Zanella

An important decrease in the soot combustion temperature was observed by employing potassium and manganese on ZrO2 as support; significantly boosted soot combustion was obtained with the K/ZrO2 and Mn–K/ZrO2 catalysts for T50 at 295 and 240 °C, respectively. The enhanced catalytic activity by using the Mn–K/ZrO2 catalyst could be attributed to the alkaline metal ion, which improved the catalyst/soot contact. XPS results revealed the presence of surface vacancies, where the addition of manganese improved the lattice oxygen and concentration of OH groups on the Mn–K/ZrO2 catalyst at low temperatures; the presence of surface vacancies was facilitated by the interaction between potassium and manganese. The Mn–K/ZrO2 catalyst showed resistance to deactivation for five cycles.



中文翻译:

促进碱性Mn / ZrO 2纳米结构上烟尘燃烧

通过在ZrO 2上使用钾和锰作为载体,可以观察到烟灰燃烧温度的显着降低。用K / ZrO 2和Mn-K / ZrO 2催化剂分别在295和240°C的T 50可获得显着促进的烟尘燃烧。通过使用Mn-K / ZrO 2催化剂提高的催化活性可以归因于碱金属离子,从而改善了催化剂/烟灰接触。XPS结果表明存在表面空位,其中添加锰改善了Mn–K / ZrO 2上的晶格氧和OH基团的浓度低温催化剂;钾和锰之间的相互作用促进了表面空位的存在。Mn-K / ZrO 2催化剂在五个循环中均表现出抗失活性。

更新日期:2020-01-25
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