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Effect of In2O3 on the structural properties and catalytic performance of the CuO/ZnO/Al2O3 catalyst in CO2 and CO hydrogenation to methanol
Molecular Catalysis ( IF 4.6 ) Pub Date : 2020-01-25 , DOI: 10.1016/j.mcat.2020.110776
Mohammad Sadeghinia , Mehran Rezaei , Ali Nemati Kharat , Majid Namayandeh Jorabchi , Behzad Nematollahi , Fazlollah Zareiekordshouli

Ternary CuO/ZnO/Al2O3 catalyst was synthesized through coprecipitation method and the effect of indium addition on the textural and catalytic performance was evaluated. The catalysts were tested at 50 atm and 250 °C in H2/CO/CO2, H2/CO and H2/CO2 feed. The presence of In2O3 resulted in structural promotions including enhanced BET and copper surface area, smaller copper crystals and increased oxygen vacancies. On the contrary, unexpected results were observed in catalytic activities in H2/CO/CO2 and H2/CO2 feeds. Pure In2O3 revealed the ability of direct hydrogenation of CO2 to methanol. In addition, it was observed that the addition of palladium into the catalyst remarkably enhanced the CO2 hydrogenation to methanol.



中文翻译:

In 2 O 3对CuO / ZnO / Al 2 O 3催化剂在CO 2和CO加氢制甲醇中的结构性能和催化性能的影响

通过共沉淀法合成了三元CuO / ZnO / Al 2 O 3催化剂,并评价了铟添加对质构和催化性能的影响。在H 2 / CO / CO 2,H 2 / CO和H 2 / CO 2进料中在50 atm和250°C下测试催化剂。In 2 O 3的存在导致结构促进,包括增加的BET和铜表面积,较小的铜晶体和增加的氧空位。相反,在H 2 / CO / CO 2和H 2 / CO 2中的催化活性观察到出乎意料的结果。饲料。Pure In 2 O 3显示了将CO 2直接氢化为甲醇的能力。另外,观察到向催化剂中添加钯显着增强了CO 2加氢为甲醇。

更新日期:2020-01-26
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