当前位置: X-MOL 学术J. Supercrit. Fluids › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Hydrogen production by supercritical water gasification of black liquor: Use of high temperatures and short residence times in a continuous reactor
The Journal of Supercritical Fluids ( IF 3.9 ) Pub Date : 2020-01-25 , DOI: 10.1016/j.supflu.2020.104772
P. Casademont , J. Sánchez-Oneto , A.P.J. Scandelai , L. Cardozo-Filho , J.R. Portela

The Supercritical Water Gasification (SCWG) of black liquor (BL) to obtain hydrogen and dispose of organic waste simultaneously has been studied in a continuous reactor employing short residence times. The experiments were conducted at 600–700 °C, with times between 24.5–29.1 s, at 23 MPa and feedstock was diluted to different concentration levels (0.81–2.43 wt.%). Furthermore, different NaOH concentrations (0–1.2 wt.%) were added to maintain a basic medium and avoid the polymerization of the compounds. Hydrogen production and COD removal was conducted with short residence times. The best results regarding hydrogen yield were achieved at 700 °C, 24.5 s residence time and 0.9 wt.% NaOH concentration, with a production of 38.68 mol H2/kgsample. In contrast, and regarding COD removal, the best results were obtained at 700 °C, with 24.5 s residence time and the highest feed COD concentration used (2.43 wt.%). The COD removal levels reached were between 65–90 %.



中文翻译:

黑液超临界水气化制氢:在连续反应器中使用高温和短停留时间

在使用短停留时间的连续反应器中,已经研究了黑液(BL)的超临界水气化(SCWG)以同时获得氢和处理有机废物的方法。实验在600-700°C的温度下进行,时间为24.5-29.1 s,时间为23 MPa,原料稀释到不同的浓度水平(0.81-2.43 wt。%)。此外,添加了不同浓度的NaOH(0-1.2 wt。%)以保持碱性介质并避免化合物的聚合。制氢和去除COD的停留时间很短。关于氢产量的最好的结果是在700°C,24.5住所时间和0.9重量%的NaOH浓度来实现,以生产38.68摩尔H的2 / kg的样品。相反,就去除COD而言,在700°C,24.5 s的停留时间和最高的进料COD浓度(2.43 wt。%)下可获得最佳结果。达到的COD去除水平在65-90%之间。

更新日期:2020-01-25
down
wechat
bug