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Performance Improvement of TiO2/CuO by Increasing Oxygen Flow Rates and Substrate Temperature Using DC Reactive Magnetron Sputtering Method
Optik ( IF 3.1 ) Pub Date : 2020-01-24 , DOI: 10.1016/j.ijleo.2020.164297
Paulina Sawicka-Chudy , Grzegorz Wisz , Maciej Sibiński , Zbigniew Starowicz , Łukasz Głowa , Maciej Szczerba , Marian Cholewa

In the present study, TiO2/CuO solar cells have been successfully fabricated for the first time using DC reactive magnetron sputtering for application in PV devices. To improve the performance of TiO2 and CuO solar cells, we increased the oxygen flow rates and substrate temperature during the deposition of TiO2 and CuO thin films compared with our previous work. The structural features by X-ray diffraction and energy-dispersive X-ray spectroscopy spectrum(s) with the atomic percent were analyzed. Next, scanning electron microscopy images with cross-sections were compared. Finally, current–voltage characteristics (I-V) capacitance–voltage (C-V) were determined. The PV parameters, open circuit voltage, short circuit current, fill factor, and efficiency, were then analyzed and compared. We observed a maximum efficiency of 0.24% and an open circuit voltage of 0.14 V. To the best of our knowledge, we attained the fourth highest efficiency reported to date. The C-V and I-V characteristics were compared with theoretical calculations obtained with the solar cell capacitance simulator, SCAPS, program.



中文翻译:

直流反应磁控溅射法提高氧气流量和衬底温度提高TiO 2 / CuO性能

在本研究中,首次使用直流反应磁控溅射成功地制造了TiO 2 / CuO太阳能电池,并将其用于光伏器件。为了提高TiO 2和CuO太阳能电池的性能,我们在TiO 2沉积过程中提高了氧气流速和基板温度与我们以前的工作相比,CuO薄膜。分析了具有原子百分数的X射线衍射和能量色散X射线光谱光谱的结构特征。接下来,比较具有横截面的扫描电子显微镜图像。最后,确定了电流-电压特性(IV)电容-电压(CV)。然后对PV参数,开路电压,短路电流,填充系数和效率进行了分析和比较。我们观察到最大效率为0.24%,开路电压为0.14V。据我们所知,我们达到了迄今为​​止报道的第四高效率。将CV和IV特性与通过太阳能电池电容模拟器SCAPS程序获得的理论计算进行了比较。

更新日期:2020-01-24
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