The electrode kinetics of hydrogen evolution reaction (HER) greatly relies on both strong water absorption and strong H atom desorption for fast electron transfer while prompting hydrogen evolution, but it is very challenging to achieve due to the tough trading off between water absorption and H-desorption ability of the catalyst. Herein, a unique high-surficial multi-heteroatomic catalytic process is realized by rationally design and tailor Ni₃Sn₂S₂ dots-decorated thin Ni₃S₂ nanosheets to form sheets-on-sheets array self-supported electrode by simple hydrothermal process. The formed Ni₃Sn₂S₂@Ni₃S₂-2 NF delivers a superior performance very close to the noble catalyst (Pt/C) at low current densities with an onset-potential of nearly 0 mV and overpotentials of 50.7 mV at 10 mA cm^-2 while surprisingly surpassing Pt/C at high current densities. The outstanding HER performance of the catalyst can be ascribed that the rationally tuned multi-heterogeneous interfaces and electronic structure control can realize both strong water absorption and strong H atom desorption to not only significantly promotes fast electron transfer, but also greatly enhances the gas release toward efficient HER. This work holds a great promise to fabricate a non-noble HER catalyst for high-performance close to the noble catalysts such as Pt/C while shedding a light on fundamentals to guide construction of high-surficial heteroatomic multi-heterogeneous catalysts with superior performance.

氢析出反应（HER）的电极动力学极大地依赖于强吸水率和强H原子解吸作用，以促进电子的快速转移，同时促进了氢的析出，但是由于吸水和H-催化剂的解吸能力。在此，通过合理设计和定制Ni ₃ Sn ₂ S ₂点修饰的薄Ni ₃ S ₂纳米片，通过简单的水热法形成片对片阵列自支撑电极，实现了独特的高表面多杂原子催化工艺。 。形成的Ni ₃ Sn ₂ S ₂ @Ni ₃ S₂ -2 NF在低电流密度下提供的性能非常接近贵金属催化剂（Pt / C），在10 mA cm ^-2时的起始电势接近0 mV，过电势为50.7 mV同时在高电流密度下令人惊讶地超过了Pt / C。催化剂杰出的HER性能可以归因于合理调整的多相界面和电子结构控制，可以实现强吸水和强H原子解吸，不仅显着促进了快速的电子转移，还大大增强了向高效的HER。这项工作很有希望制造出与贵金属催化剂（如Pt / C）接近的高性能非贵金属HER催化剂，同时阐明基本原理，以指导具有优异性能的高表面异质多异质催化剂的构建。