当前位置: X-MOL 学术Eur. J. Org. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Visible‐Light‐Promoted Metal‐Free C‐H Trifluoromethylation of Imidazopyridines
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-02-13 , DOI: 10.1002/ejoc.201901860
Xia Mi 1 , Yuanfang Kong 1 , Huaixia Yang 1 , Jingyu Zhang 1 , Chao Pi 2 , Xiuling Cui 2
Affiliation  

An efficient, mild and photo redox‐based protocol for the C–H trifluoromethylation of imidazo[1,2‐a]pyridines has been developed using acridinium as photo redox catalyst and the easy‐handling CF3SO2Na as CF3 source. A series of desired products were afforded in satisfied yields under transition‐metal‐free condition, which displays potential for further application in synthetic research.
image


中文翻译:

咪唑并吡啶的可见光促进无金属C-H三氟甲基化

已经开发了一种高效,温和且基于光氧化还原的协议,该方法使用cri啶作为光氧化还原催化剂,并使用易于处理的CF 3 SO 2 Na作为CF 3来源,开发了咪唑并[1,2- a ]吡啶的CHH三氟甲基化反应。在无过渡金属的条件下,以令人满意的产率提供了一系列所需的产品,这显示了在合成研究中进一步应用的潜力。
图片
更新日期:2020-02-14
down
wechat
bug