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Fe3+ stabilized 3D cross-linked glycine-melamine formaldehyde networks as precursor for highly efficient oxygen reduction catalyst in alkaline media
Materials Letters ( IF 3 ) Pub Date : 2020-04-01 , DOI: 10.1016/j.matlet.2020.127365
Shijina Kottarathil , Rajith Illathvalappil , Nisa S. , Sailaja G.S. , Peer Mohamed A. , Balagopal N. Nair , Anilkumar Gopinathan M. , Sreekumar Kurungot , Takeo Yamaguchi , Hareesh U.S.

Abstract Development of inexpensive oxygen reduction electrocatalyst with high activity and durability is very important. Herein, iron carbide encapsulated pod-like graphitic carbon structures were prepared by simple pyrolysis involving Fe-glycine complex integrated melamine–formaldehyde resin precursor. The best catalyst among those studied, Fe-Gly 2 MF-C, possessing high degree of graphitization (ID/IG = 0.99) and enhanced specific surface area (205 m2/g) exhibited the highest ORR activity with a half-wave potential of 0.80 V in alkaline medium through the four-electron reduction pathway.

中文翻译:

Fe3+ 稳定的 3D 交联甘氨酸-三聚氰胺甲醛网络作为碱性介质中高效氧还原催化剂的前体

摘要 开发具有高活性和耐久性的廉价氧还原电催化剂非常重要。在此,碳化铁封装的豆荚状石墨碳结构是通过简单的热解制备的,涉及 Fe-甘氨酸复合物集成的三聚氰胺-甲醛树脂前体。研究中最好的催化剂 Fe-Gly 2 MF-C 具有高度石墨化 (ID/IG = 0.99) 和增强的比表面积 (205 m2/g),表现出最高的 ORR 活性,半波电位为0.80 V 在碱性介质中通过四电子还原途径。
更新日期:2020-04-01
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