Abstract A round-cake like {Fe24} coordination cage is assembled by bridging six Fe4-p-tert-butylthiacalix[4]arene (Fe4-TC4A) SBUs with sulfate and chloride anions. The structure can also be thought to form by bolstering two {(Fe4-TC4A)3-(μ3-Cl−)} coordination triangles rotating 60° from each other with sulfate and chloride anions. Its magnetic property was studied. Moreover, no analogous of cobalt and nickel was obtained but some isolated chair-like {Co8}/{Ni8} entities.

中文翻译：

---

一个杯芳烃加盖的圆饼，如 {Fe24} 配位笼，包括像羽毛球一样的 Fe4-TC4A SBU

摘要 通过将六个 Fe4-p-叔丁基硫代杯 [4] 芳烃 (Fe4-TC4A) SBU 与硫酸根和氯根阴离子桥接，组装了一个类似 {Fe24} 配位笼的圆饼。该结构也可以被认为是通过支持两个 {(Fe4-TC4A)3-(μ3-Cl−)} 配位三角形与硫酸根和氯根阴离子相互旋转 60° 形成的。对其磁性进行了研究。此外，没有获得类似的钴和镍，而是获得了一些孤立的椅子状 {Co8}/{Ni8} 实体。