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Intensification of lyocell dissolution process and dope characteristics using pre-swelled cellulosic pulp
Chemical Engineering and Processing: Process Intensification ( IF 4.3 ) Pub Date : 2020-01-20 , DOI: 10.1016/j.cep.2020.107826
Anwar J. Sayyed , Lalaso V. Mohite , Niteen A. Deshmukh , Dipak V. Pinjari

Transformation of pulp into regenerated lyocell fibre involves a critical step of cellulose dissolution in aqueous NMMO solution. The objective of this work is to investigate the effect of using pre-swelled pulps derived from hardwood kraft sulphate (H-KS) and softwood kraft sulphate (S-KS) process, on cellulose dissolution. Pre-swelling at temperatures follows from 30 °C to 75 °C results in lowering of pulp crystallinity, and hence, was hypothesized to form a homogeneous solution with lower power consumption during the dissolution process. Experimental torque moments (proportional to power consumption) of the un-swelled and pre-swelled pulps at different temperatures were compared and correlated with the cellulose dissolution process. Further, a time based morphological study of cellulose dissolution was performed with the help of a microscopic investigation method. The quality of the dissolved dope was evaluated by optical image analysis, refractive index (RI), dope composition and thermal analysis (TGA/DSC). It was observed that by using pre-swelled pulps, homogeneous cellulose solution could be formed at lower processing temperature, consuming less time and power thereby making the lyocell process more energy-efficient and sustainable.



中文翻译:

使用预溶胀的纤维素纸浆强化莱细胞溶解过程和浓液特性

纸浆转化为再生的莱赛尔纤维涉及纤维素在NMMO水溶液中溶解的关键步骤。这项工作的目的是研究使用源自硬木硫酸盐硫酸盐(H-KS)和软木硫酸盐硫酸盐(S-KS)工艺的预溶浆对纤维素溶解的影响。在30°C至75°C的温度下进行预溶胀会降低纸浆的结晶度,因此,据推测在溶解过程中会形成具有较低功耗的均质溶液。比较了在不同温度下未溶胀和预溶浆的实验扭矩(与功率消耗成比例),并将其与纤维素溶解过程相关联。进一步,借助显微镜研究方法,进行了基于时间的纤维素溶解形态学研究。通过光学图像分析,折射率(RI),涂料组成和热分析(TGA / DSC)评估溶解的涂料的质量。观察到,通过使用预溶胀的纸浆,可以在较低的加工温度下形成均质的纤维素溶液,消耗更少的时间和功率,从而使莱赛尔工艺更加节能和可持续。

更新日期:2020-01-20
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