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Molecular tectonics: Self-assembly of pyridyl bearing nucleobases
Tetrahedron ( IF 2.1 ) Pub Date : 2020-01-20 , DOI: 10.1016/j.tet.2020.130966
Elsa Tufenkjian , Abdelaziz Jouaiti , Nathalie Kyritsakas , Mir Wais Hosseini , Veronique Bulach

A library of organic tectons (13 and 5) combining nucleobases and a pyridyl moiety connected at the position 4 of the ring was designed and synthesized. The solid-state structure of tectons 13 was investigated by X-ray diffraction on single crystal. Owing to the self-complementary nature of the tectons bearing both H-bond donor and acceptor sites, compounds 13 self-assemble into H-bonded networks. The dimension of the latter is further increased when taking into account π-π stacking interactions.



中文翻译:

分子构造:带有吡啶基的核碱基的自组装

的有机tectons阿库(1 - 35)相结合的核碱基,并在该环的4位连接的吡啶基部分被设计并合成。tectons的固态结构1 - 3通过单晶X射线衍射进行了研究。由于tectons轴承二者H-键供体和受体位点,的自互补性的化合物1 - 3自组装成氢键网络。当考虑到π-π堆叠相互作用时,后者的尺寸进一步增加。

更新日期:2020-01-21
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