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Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials
Journal of the American Chemical Society ( IF 15.0 ) Pub Date : 2020-01-17 , DOI: 10.1021/jacs.9b10678 Hyunwoo Kim 1 , Hyungjun Kim 2 , Tristan H Lambert 1 , Song Lin 1
Journal of the American Chemical Society ( IF 15.0 ) Pub Date : 2020-01-17 , DOI: 10.1021/jacs.9b10678 Hyunwoo Kim 1 , Hyungjun Kim 2 , Tristan H Lambert 1 , Song Lin 1
Affiliation
We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of -3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (Ered ≈ -1.9 to -2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.
中文翻译:
还原电光催化:结合电和光以实现极端的还原潜力
我们描述了一种新的电光催化策略,该策略利用光和电的力量产生还原电位为 -3.2 V vs SCE 的激发自由基阴离子,可用于激活具有非常高还原电位(Ered ≈ -1.9 至 - 2.9 伏)。所得芳基可参与各种合成有用的转化,以提供芳基硼酸酯、芳基锡烷和联芳基产物。
更新日期:2020-01-17
中文翻译:
还原电光催化:结合电和光以实现极端的还原潜力
我们描述了一种新的电光催化策略,该策略利用光和电的力量产生还原电位为 -3.2 V vs SCE 的激发自由基阴离子,可用于激活具有非常高还原电位(Ered ≈ -1.9 至 - 2.9 伏)。所得芳基可参与各种合成有用的转化,以提供芳基硼酸酯、芳基锡烷和联芳基产物。