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Ultrahigh strength Mg-Y-Ni alloys obtained by regulating second phases
Journal of Materials Science & Technology ( IF 10.9 ) Pub Date : 2020-01-17 , DOI: 10.1016/j.jmst.2019.11.026
S.Z. Wu , X.G. Qiao , M.Y. Zheng

Mg-Y-Ni alloys with different second phases were designed by changing Y/Ni atomic ratio from 1.5 to 0.5. The microstructure and mechanical properties of as-cast and as-extruded alloys were investigated. The as-cast Mg-Y-Ni alloy with Y/Ni ratio of 1.5 is composed of α-Mg and long period stacking ordered (LPSO) phase. When Y/Ni ratio is equal to 1, nanoscale lamellar γ' phase and eutectic Mg2Ni phase are formed in addition to LPSO phase. As Y/Ni ratio decreases further, the amount of eutectic Mg2Ni phase increases, while the amount of LPSO phase decreases. After extrusion, the LPSO and γ' phases are distributed along the extrusion direction, while eutectic Mg2Ni phase is broken and dispersed in the as-extruded alloys. LPSO phase and Mg2Ni phase in the alloys promote dynamic recrystallization (DRX) during extrusion, while γ' phase inhibits DRX. Consequently, the Mg96Y2Ni2 (at.%) alloy with LPSO phase and γ' phase as the main second phases shows the strongest basal texture after extrusion. The tensile yield strength of the as-extruded Mg-Y-Ni alloys increases first and then decreases with decreasing Y/Ni ratio. The as-extruded Mg96Y2Ni2 (at.%) alloy with Y/Ni = 1 exhibits excellent mechanical properties with tensile yield strength of 465 MPa, ultimate tensile strength of 510 MPa and elongation to failure of 7.2%, which is attributed to the synergistic effect of bulk LPSO phase and nanoscale γ' phase.



中文翻译:

通过调节第二相获得的超高强度Mg-Y-Ni合金

通过将Y / Ni原子比从1.5更改为0.5来设计具有不同第二相的Mg-Y-Ni合金。研究了铸态和挤压态合金的显微组织和力学性能。Y / Ni比为1.5的Mg-Y-Ni铸态合金由α-Mg和长周期有序相(LPSO)相组成。当Y / Ni比等于1时,除了LPSO相之外,还形成了纳米级层状γ′相和低共熔Mg 2 Ni相。随着Y / Ni比的进一步降低,共晶Mg 2 Ni相的量增加,而LPSO相的量减少。挤压后,LPSO和γ'相沿挤压方向分布,而共晶Mg 2 Ni相破碎并分散在刚挤压的合金中。LPSO相和Mg 2合金中的Ni相促进挤压过程中的动态再结晶(DRX),而γ'相则抑制DRX。因此,以LPSO相和γ'相为主要第二相的Mg96Y2Ni2(at。%)合金在挤压后表现出最强的基础组织。挤压后的Mg-Y-Ni合金的拉伸屈服强度先增加,然后随着Y / Ni比的降低而降低。Y / Ni = 1的Mg96Y2Ni2(at。%)挤压态合金具有出色的机械性能,拉伸屈服强度为465 MPa,极限抗拉强度为510 MPa,断裂伸长率为7.2%,这归因于协同效应LPSO相和纳米级γ'相的分布。

更新日期:2020-01-17
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