Nickel-catalyzed asymmetric hydrogenation of several types of alkenes proceeds in high enantioselectivity, using acetic acid or water as the hydrogen source and indium powder as electron donor. The scope of alkenes herein include α,β-unsaturated esters, nitriles, and ketones as well as allylic alcohols. Asymmetric deuteration of α,β-unsaturated esters is also achieved with deuterated water, the cheapest deuterium source.

中文翻译：

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镍催化烯烃的不对称Umpolung加氢和氘代。

使用乙酸或水作为氢源，铟粉作为电子给体，镍催化几种烯烃的不对称氢化反应以高对映选择性进行。本文中烯烃的范围包括α，β-不饱和酯，腈和酮以及烯丙醇。α，β-不饱和酯的不对称氘化也可以通过氘水（最便宜的氘源）实现。