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Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation.
ACS Omega ( IF 4.1 ) Pub Date : 2019-12-18 , DOI: 10.1021/acsomega.9b03577
Ce Du 1, 2 , Peng Lu 1 , Noritatsu Tsubaki 2
Affiliation  

Carbon monoxide (CO) hydrogenation is an important step for efficient utilization of carbon resources in C1 (one carbon) chemistry. Over recent years, this direction has been a hot research area in academia and industry and has also been one of the most challenging routes for the nonoil carbon resources utilization process. A large number of novel reaction routes and catalysts have been studied and reported. Efficient activation and directional conversion of CO are key aspects in the process of CO utilization. Furthermore, effectively activating C-O and C-C bond formation as well as controlling carbon chain growth is the current technical bottleneck of CO hydrogenation. This mini-review introduces the latest research progress for different catalyst systems and processes in CO hydrogenation and analyzes the factors that control the performance of catalysts in different reaction systems. Here, much focus is put on the synthesis of long-chain hydrocarbons, light olefins, C2+ oxygenates, and aromatics, essentially in comparison with the previous reports. Finally, the present challenges and future research directions have been discussed.

中文翻译:

一氧化碳加氢的化学和液体燃料的高效和新生产方法。

一氧化碳(CO)加氢是有效利用C1(一种碳)化学物质中碳资源的重要步骤。近年来,这个方向一直是学术界和工业界的研究热点,也是非石油碳资源利用过程中最具挑战性的途径之一。已经研究和报道了大量新颖的反应路线和催化剂。CO的有效激活和定向转换是CO利用过程中的关键方面。此外,有效活化CO和CC键的形成以及控制碳链的生长是CO氢化的当前技术瓶颈。这份小型综述介绍了CO加氢过程中不同催化剂体系和工艺的最新研究进展,并分析了控制不同反应体系中催化剂性能的因素。与以前的报道相比,这里的重点是长链烃,轻质烯烃,C2 +含氧化合物和芳烃的合成。最后,讨论了当前的挑战和未来的研究方向。
更新日期:2020-01-14
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