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π‐Conjugated Triazenes and Nitriles: Simple Photoinduced Synthesis of Anilides Using Mild and Metal‐Free Conditions
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2020-01-21 , DOI: 10.1002/ajoc.201900721
Enrique Barragan 1 , Anurag Noonikara‐Poyil 1 , Alejandro Bugarin 2
Affiliation  

A simple, clean, direct, photochemical, and metal‐free approach to produce structurally diverse anilides in good to excellent yields (up to 99%), by utilizing π‐conjugated triazene reactivity and simple nitriles is presented. Interestingly, natural sunlight is also shown to provide effective delivery of amides, with yields up to 99%.

中文翻译:

π共轭三氮烯和腈:使用温和无金属条件简单地光诱导合成苯甲酸酯

提出了一种简单,干净,直接,光化学和无金属的方法,该方法可利用π共轭三氮烯反应性和简单的腈,以良好至极好的收率(高达99%)生产结构多样的苯胺。有趣的是,自然光还显示出酰胺的有效递送,产率高达99%。
更新日期:2020-04-21
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