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Synthesis of a Conductive Glassy System Based on Inorganic Oxides and Carbon Materials and Their Possible Electroanalytical Application
Journal of Inorganic and Organometallic Polymers and Materials ( IF 4 ) Pub Date : 2020-01-13 , DOI: 10.1007/s10904-019-01434-3
Gastón Darío Pierini , Pablo Emanuel di Pratula , Ana Laura Ochoa , María Eugenia Centurión , Marisa Alejandra Frechero , María Susana Di Nezio

New materials based on V2O5, TeO2 and a combination of graphite, graphene oxide and multiwalled carbon nanotubes were developed and tested as potential electrochemical sensors. A mixture design with three components in combination with multi-response assays based on the desirability function was used as multivariate optimization for the system composition. The optimal sensor contains graphene oxide and multiwalled carbon in approximately equal amounts. The new sensors characterizations were performed with X-ray diffraction, differential scanning calorimetry, impedance spectroscopy and cyclic voltammetry. The main advantage of this electrodes are does not requires surface activation and exhibited a potential electroanalytical performance with different targeted analytes such as ascorbic acid, aspartame and lead.

中文翻译:

基于无机氧化物和碳材料的导电玻璃态体系的合成及其可能的电分析应用

基于V 2 O 5,TeO 2的新材料并开发了石墨,氧化石墨烯和多壁碳纳米管的组合,并作为潜在的电化学传感器进行了测试。具有三个成分的混合物设计与基于期望函数的多响应分析相结合,被用作系统组成的多变量优化。最佳传感器包含近似相等数量的氧化石墨烯和多壁碳。使用X射线衍射,差示扫描量热法,阻抗谱和循环伏安法进行了新的传感器表征。该电极的主要优点是不需要表面活化,并且在不同的目标分析物(例如抗坏血酸,阿斯巴甜和铅)下表现出潜在的电分析性能。
更新日期:2020-01-13
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