Four new cesium-containing cobalt oxide complexes were reported. Cs(Co_0.5Si_0.5)SiO₄ (1), Cs_1.29(5)Co_0.69(5)Ge_1.81(5)O₅ (2), and its ordered analogue Cs₂CoGe₄O₁₀ (3) were synthesized using a mixed CsCl–CsF flux at 850 °C or 900 °C. The structure of (1) closely resembles that of known zeolite and feldspar structures, and (1) crystallizes in the noncentrosymmetric monoclinic space group Im with lattice parameters of a = 8.9926(4) Å, b = 5.4599(2) Å, c = 9.3958(6) Å, and β = 91.5928(18)°. Complexes (2) and (3) crystallize in the same new structure with a highly porous three-dimensional framework in the tetragonal space group I with lattice parameters of a = 7.4239(14) Å and c = 13.169(3) Å for (2) and a = 7.3540(6) Å and c = 13.1122(11) Å for (3). The formation of (2) vs. (3) can be controlled based on slight variations in the quantities of the starting materials. Single-crystal-to-single-crystal ion exchange of (1) in a molten RbNO₃ bath resulted in 14% Cs exchange with Rb, affording the composition Cs_0.86Rb_0.14(Co_0.5Si_0.5)SiO₄ (4). First-principles density functional theory calculations were performed to elucidate the electronic and magnetic properties and stabilities of (1) and (3) at 0 K.

中文翻译：

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复杂的硅酸钴和锗酸盐在多孔三维骨架结构中结晶

据报道有四种新的含铯的氧化钴配合物。Cs（Co _0.5 Si _0.5）SiO ₄（1），Cs _1.29（5） Co _0.69（5） Ge _1.81（5） O ₅（2）及其有序类似物Cs ₂ CoGe ₄ O ₁₀（3）的合成在850°C或900°C下混合的CsCl–CsF通量。的结构（1）非常类似于已知的沸石和长石的结构，及（1）的非中心对称斜空间群中结晶林与晶格参数一＝ 8.9926（4），b＝ 5.4599（2），c＝ 9.3958（6），和β＝ 91.5928（18）°。络合物（2）和（3）在相同的新结构中以高度多孔的三维骨架在四方空间群I中结晶，晶格参数为（2）a = 7.4239（14）Å和c = 13.169（3）Å ），对于（3），a = 7.3540（6）Å，c = 13.1122（11）Å 。（2）vs.（3的形成）可以根据原料的少量变化进行控制。（1）在熔融的RbNO ₃浴中的单晶至单晶离子交换导致与Rb的Cs交换率为14％，提供了组成Cs _0.86 Rb _0.14（Co _0.5 Si _0.5）SiO ₄（4）。进行了第一性原理密度泛函理论计算，以阐明（1）和（3）在0 K时的电子和磁性及稳定性。