Ti4(embonate)6 Cage-Ligand Strategy on the Construction of Metal-Organic Frameworks with High Stability and Gas Sorption Properties.,Inorganic Chemistry

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Ti4(embonate)6 Cage-Ligand Strategy on the Construction of Metal-Organic Frameworks with High Stability and Gas Sorption Properties.
Inorganic Chemistry ( IF 4.6 ) Pub Date : 2020-01-09 , DOI: 10.1021/acs.inorgchem.9b03075
Yan-Ping He ₁ , Guang-Hui Chen ₁ , Lv-Bing Yuan ₁ , Lei Zhang ₁ , Jian Zhang ₁

Affiliation

Herein we report an efficient strategy to construct cage-based metal-organic frameworks (MOFs) via the assembly of Ti4L6 (L = embonate) cages and N-contained ligands with Mn2+ and Zn2+ ions, respectively, and two Ti4L6-cage-based MOFs (PTC-219 and PTC-220) with high stability and gas sorption properties have been generated through two-step reactions, respectively.

中文翻译：

Ti4（embonate）6笼-配体策略，用于构建具有高稳定性和气体吸附特性的金属-有机骨架。

在本文中，我们报告了一种有效的策略，通过组装Ti4L6（L =精酸盐）笼子和N配体，分别带有Mn2 +和Zn2 +离子和两个基于Ti4L6笼子的MOF来构建基于笼子的金属有机框架（MOF）具有高稳定性和气体吸附特性的三氟乙烯（PTC-219和PTC-220）分别通过两步反应生成。

更新日期：2020-01-10

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