当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C-F Coupling of Aryl Boronic Esters.
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2020-01-09 , DOI: 10.1002/anie.201914729
Daniel Janssen-Müller 1 , Martin Oestreich 1
Affiliation  

The main-group age: The past decade has revealed main-group-element compounds that display transition-metal-like reactivity in stoichiometric and even catalytic transformations. Cornella and co-workers have now reported a bismuth complex that catalyzes fluoroarene formation from aryl boronate esters, a reaction that is almost unprecedented in transition-metal catalysis.

中文翻译:

具有主族元素的类似过渡金属的催化:芳基硼酸酯的铋催化CF偶联。

主族时代:过去十年发现了主族元素化合物,它们在化学计量甚至催化转化中都表现出类似过渡金属的反应性。Cornella及其同事现在报道了一种铋络合物,该络合物催化由芳基硼酸酯生成氟代芳烃,这种反应在过渡金属催化中几乎是前所未有的。
更新日期:2020-01-09
down
wechat
bug