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C- to N-Center Remote Heteroaryl Migration via Electrochemical Initiation of N Radical by Organic Catalyst.
Organic Letters ( IF 5.2 ) Pub Date : 2020-01-10 , DOI: 10.1021/acs.orglett.9b04141
Chengkou Liu 1 , Qiang Jiang 1 , Yang Lin 1 , Zheng Fang 1 , Kai Guo 1, 2
Affiliation  

Herein an exogenous oxidant- and metal-free electrochemical heteroaryl migration triggered by N radicals to construct new N-C bonds was developed. This methodology features a high atom economy and utilization rate of energy, and it is insensitive to water and air. Moreover, a user-friendly undivided cell was employed. The use of an organic catalyst makes it more efficient, green, and practical.

中文翻译:

通过有机催化剂通过N自由基的电化学引发从C到N中心的远程杂芳基迁移。

在这里,开发了由N自由基引发的无氧化剂和无金属的电化学杂芳基迁移,以构建新的NC键。该方法具有高原子经济性和能源利用率的特点,并且对水和空气不敏感。此外,使用了用户友好的未分割单元。有机催化剂的使用使其更有效,绿色和实用。
更新日期:2020-01-10
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