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Design of AgNPs -Base Starch/PEG-Poly (Acrylic Acid) Hydrogel for Removal of Mercury (II)
Journal of Polymers and the Environment ( IF 5.3 ) Pub Date : 2020-01-10 , DOI: 10.1007/s10924-020-01651-9
Atefeh Saberi , Mohammad Sadeghi , Eskandar Alipour

In the present study, we introduce the formation of Starch/PEG-poly (acrylic acid) hydrogel (St-PEG-AcAH) and nanocomposite of AgNPs-base St-PEG-AcAH (AgNPs-St-PEG-AcANCH) free radical method, and their characterization using analytical techniques of FT-IR, TEM, SEM, EDX, AFM, XRD, TGA/DTG. The thermodynamic parameters and application of prepared hydrogels was investigated for the removal of Hg2+ ions in water and the various solvents such as ethanol-water (30:70), ethanol-water (50:50), 2-propanol–water (40:60), respectively. The maximum adsorption capacity of Hg2+ ions for St-PEG-AcAH and AgNPs-St-PEG-AcANCH was achieved 158.21 mg/g and 182.53 mg/g in pH 7 and 6 in aqueous solutions, respectively. On the other hand, the results of adsorption isotherms revealed that adsorption process for both adsorbents occurred as a homogenous and monolayer process with L-shape isotherm. Furthermore, investigating the bioactivity of bioadsorbents, the good antimicrobial efficiency of the prepared samples was confirmed on E. coli bacteria.



中文翻译:

AgNPs基淀粉/ PEG-聚(丙烯酸)水凝胶的去除汞设计(II)

在本研究中,我们介绍了淀粉/ PEG-聚(丙烯酸)水凝胶(St-PEG-AcAH)的形成和基于AgNPs的St-PEG-AcAH(AgNPs-St-PEG-AcANCH)纳米复合材料的自由基合成方法,以及使用FT-IR,TEM,SEM,EDX,AFM,XRD,TGA / DTG的分析技术对其进行表征。热力学参数和制备的水凝胶的应用进行了研究用于去除汞2+在水中离子和各种溶剂如乙醇-水(30:70),乙醇-水(50:50),2-丙醇-水( 40:60)。Hg 2+的最大吸附量在水溶液中,pH 7和6时,St-PEG-AcAH和AgNPs-St-PEG-AcANCH的离子分别达到158.21 mg / g和182.53 mg / g。另一方面,吸附等温线的结果表明,两种吸附剂的吸附过程均发生在L形等温线的均质和单层过程中。此外,通过研究生物吸附剂的生物活性,证实了所制备样品对大肠杆菌具有良好的抗菌效率。

更新日期:2020-01-10
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