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Site-Selective Rh-Catalyzed C-7 and C-6 Dual C-H Functionalization of Indolines: Synthesis of Functionalized Pyrrolocarbazoles.
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2020-01-17 , DOI: 10.1021/acs.joc.9b03180
Sonbidya Banerjee 1 , Sundaravel Vivek Kumar 1 , Tharmalingam Punniyamurthy 1
Affiliation  

A site-selective dual C-7 and C-6 C-H functionalization of indolines with azabenzonorbornadienes has been accomplished using Rh-catalysis. The reaction affords a potential route toward pyrrolocarbazoles with broad scope and functional group tolerance.

中文翻译:

定点Rh催化的C-7和C-6吲哚的双CH功能化:官能化的吡咯并咔唑的合成。

使用Rh催化已经完成了用氮杂苯并降冰片二烯对二氢吲哚进行定点选择性C-7和C-6 CH双官能化。该反应提供了向吡咯并咔唑的潜在途径,其具有宽范围和官能团耐受性。
更新日期:2020-01-17
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