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Microstructure and tensile properties of Zr-containing ODS-FeCrAl alloy fabricated by laser additive manufacturing
Materials Science and Engineering: A ( IF 6.4 ) Pub Date : 2020-01-09 , DOI: 10.1016/j.msea.2020.138937
Yingnan Shi , Zheng Lu , Li Yu , Rui Xie , Yuhang Ren , Guang Yang

Oxide dispersion strengthened (ODS) FeCrAl alloys have been considered as the promising candidate fuel cladding materials for the Gen-IV fission reactors due to excellent radiation tolerance, mechanical properties and corrosion resistance, but their manufacturing is complex process. Laser engineered net shaped (LENS) technology followed by post-build heat treatment was employed successfully to fabricate Zr-containing ODS-FeCrAl alloy. The microstructure of as-deposited and heat-treated alloys was characterized by optical microscope (OM), electron backscatter diffraction (EBSD), scanning electron microscope (SEM) and high-resolution transmission electron microscope (HRTEM). The tensile tests were carried out at room temperature. The results show that the coarse columnar grains with preferred orientation ([001] fibre texture) are obtained after LENS deposit and are remained after post-build heat treatment. The average width of columnar grains for both as-deposited and heat-treated samples is ∼180–190 μm. A slag-like layer which is made up of Y3Al5O12, ZrO2 and Al2O3 is observed at the surface of deposited sample. Some coarse appendage oxides which consist of Al2O3 and Y4Zr3O12 are distributed in the matrix of as-deposited sample. Post-build heat treatment produces high-density nanoscale Y4Zr3O12 oxides in the matrix. The formation mechanism of different type oxides is explained. Both as-deposited and heat-treated samples present anisotropic tensile properties. After post-build heat treatment, the tensile strength is improved significantly by the formation of high-density nanoscale Y4Zr3O12.



中文翻译:

激光增材制造含Zr的ODS-FeCrAl合金的组织和拉伸性能

氧化物弥散强化(ODS)FeCrAl合金由于具有出色的耐辐射性,机械性能和耐蚀性,因此被认为是第四代裂变反应堆的有希望的候选燃料包覆材料,但它们的制造工艺复杂。成功地采用激光工程网状(LENS)技术,然后进行后加工热处理,以制造含Zr的ODS-FeCrAl合金。通过光学显微镜(OM),电子背散射衍射(EBSD),扫描电子显微镜(SEM)和高分辨率透射电子显微镜(HRTEM)对沉积和热处理合金的微观结构进行了表征。拉伸试验在室温下进行。结果表明,在LENS沉积后获得具有优选取向([001]纤维织构)的粗柱状晶粒,并在后热处理后保留。沉积和热处理样品的柱状晶粒平均宽度约为180-190μm。由Y组成的渣状层在沉积样品的表面观察到3 Al 5 O 12,ZrO 2和Al 2 O 3。一些由Al 2 O 3和Y 4 Zr 3 O 12组成的粗附氧化物分布在沉积后的样品基体中。建置后热处理可产生高密度纳米级Y 4 Zr 3 O 12基质中的氧化物。说明了不同类型氧化物的形成机理。沉积样品和热处理样品均具有各向异性拉伸性能。在构建后的热处理之后,通过形成高密度的纳米级Y 4 Zr 3 O 12可以显着提高拉伸强度。

更新日期:2020-01-09
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